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The c-phosphanylimine L1 was employed for the synthesis of the novel titanaaziridine 1 with an intramolecular phosphine donor side following a reductive complexation route. This coordination mode is new for c-phosphanylimines and compound 1 is the first group 4 complex featuring a c-phosphanylimine ligand.

Original publication

DOI

10.1039/c8dt04918a

Type

Journal article

Journal

Dalton Transactions

Publication Date

01/01/2019

Volume

48

Pages

1936 - 1940